Material Safety Data Sheet
Tris Glycine SDS 10X Powder
ACC# 45458
Section 1 - Chemical Product and Company Identification |
MSDS Name: Tris Glycine SDS 10X Powder
Catalog Numbers:
BP1342-1
Synonyms:
Tris-Glycine-Sodium Lauryl Sulfate Powder
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
56-40-6 |
Glycine |
82.3 | 200-272-2 |
77-86-1 |
Tris (hydroxymethyl) aminomethane |
17.1 | 201-064-4 |
151-21-3 |
Sodium lauryl sulfate |
<1 | 205-788-1 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: white solid.
Caution! May cause eye, skin, and respiratory
tract irritation.
Target Organs: None known.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Low hazard for usual industrial handling.
Inhalation:
Low hazard for usual industrial handling. Inhalation of a mist of
this material may cause respiratory tract irritation.
Chronic:
No information found.
Section 4 - First Aid Measures
|
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid if irritation develops or persists. Wash clothing
before reuse. Flush skin with plenty of soap and water.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use alcohol foam, carbon dioxide, or water spray when fighting fires
involving this material.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 1; Flammability: 0; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Keep containers tightly closed.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Glycine
|
none listed
|
none listed
|
none listed
|
Tris (hydroxymethyl) aminomethane
|
none listed
|
none listed
|
none listed
|
Sodium lauryl sulfate
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
Glycine:
No OSHA Vacated PELs are listed for this chemical.
Tris (hydroxymethyl) aminomethane:
No OSHA Vacated PELs are listed for this chemical.
Sodium lauryl sulfate:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Solid
Appearance: white
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Soluble in water.
Specific Gravity/Density:Not available.
Molecular Formula:Mixture
Molecular Weight:Not available.
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 56-40-6:
MB7600000
CAS# 77-86-1:
TY2900000
CAS# 151-21-3:
WT1050000
LD50/LC50:
CAS# 56-40-6:
Oral, mouse: LD50 =
4920 mg/kg;
Oral, rat: LD50 = 7930
mg/kg;
.
CAS# 77-86-1:
Oral, rat: LD50
= 5900 mg/kg;
.
CAS# 151-21-3:
Draize test,
rabbit, eye: 100 mg/24H Moderate;
Draize test, rabbit, eye: 250 ug
Mild;
Draize test, rabbit, eye: 2
mg;
Draize test, rabbit, eye: 10 mg
Moderate;
Draize test, rabbit,
skin: 50 mg/24H Severe;
Draize
test, rabbit, skin: 25 mg/24H Moderate;
Draize test, rabbit, skin: 250 mg/24H
Moderate;
Draize test, rabbit,
skin: 10 mg/24H;
Draize test,
rabbit, skin: 50 mg/24H Mild;
Inhalation, rat: LC50 = >3900
mg/m3/1H;
Oral, rat: LD50 = 1288
mg/kg;
.
Carcinogenicity:
CAS# 56-40-6:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 77-86-1:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 151-21-3:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information found
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
|
Ecotoxicity:
No data available.
No information available.
Environmental:
No information found.
Physical:
No information found.
Other:
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
Not regulated. |
Not regulated. |
Hazard Class: |
|
|
UN Number: |
|
|
Packing Group: |
|
|
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 56-40-6 is listed on the TSCA inventory.
CAS# 77-86-1 is listed on the TSCA inventory.
CAS# 151-21-3 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 77-86-1: immediate.
CAS # 151-21-3: immediate.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 56-40-6 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 77-86-1 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 151-21-3 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
Not available.
Risk Phrases:
Safety Phrases:
S 22 Do not breathe dust.
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 56-40-6: 0
CAS# 77-86-1: 1
CAS# 151-21-3: 2
Canada - DSL/NDSL
CAS# 56-40-6 is listed on Canada's DSL List.
CAS# 77-86-1 is listed on Canada's DSL List.
CAS# 151-21-3 is listed on Canada's DSL List.
Canada - WHMIS
not available.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 151-21-3 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 7/15/1999
Revision #5 Date: 10/29/2007
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.